发明名称 CONVERSION OF ALKANES HAVING AT MOST 5 CARBONATOMS TO ALCOHOLS AND/OR ALDEHYDES USING A PLATINUM COMPLEX CATALYST
摘要 A gas-phase process is provided for catalytic conversion of a lower alkane comprising at most 5 carbon atoms to at least one produce selected from the group consisting of alcohols, aldehydes and mixtures thereof. The process comprises bringing said lower alkane into contact with an oxidising agent in the presence of a catalyst comprising at least one platinum complex. The invention also provides such catalyst for use in the process. The catalyst comprises a platinum complex having a platinum cation core. It has two ligands selected from amino ligands, hydroxyl ligands and immidazolyl ligands whereby the complex is bonded chemically to a metal oxide support. It also has four other ligands selected from hydroxyl ligands, chloro ligands and amino ligands.
申请公布号 WO2005037746(A1) 申请公布日期 2005.04.28
申请号 WO2004IB03319 申请日期 2004.10.12
申请人 ESKOM HOLDINGS LIMITED;LINKOV, VLADIMIR MIKHAILOVICH;BELYAKOV, VLADIMIR NIKOLAEVICH;BELYAKOV, LUDMILA ALEKSEEVNA 发明人 LINKOV, VLADIMIR MIKHAILOVICH;BELYAKOV, VLADIMIR NIKOLAEVICH;BELYAKOV, LUDMILA ALEKSEEVNA
分类号 B01J23/42;B01J31/02;B01J31/16;B01J31/18;B01J31/22;C07C27/14;C07C29/50;C07C45/33 主分类号 B01J23/42
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