发明名称 Dibenzocycloheptene derivatives
摘要 The invention comprises compounds of the formula <FORM:1119377/C2/1> wherein each of X and X1 represents a hydrogen atom or a C1- 4 perfluoroalkyl or C1- 4 alkyl-sulphonyl radical, and process wherein a 5-allylidene -10, 11 - dihydro - 5H - dibenzo[a, d] cycloheptene is reacted with a peracid to form the corresponding 5 - (2,3 - epoxypropylidene) - derivative; the latter is rearranged in the presence of an acid catalyst to the corresponding 5 - (3 - oxopropylidene) - derivative - and said oxo-compound is reductively aminated with monomethylamine or dimethylamine to give a 5 - (mono- or di-methylaminopropylidene) 10,11 - dihydro - 5H - dibenzo(a,d)cycloheptene.
申请公布号 GB1119377(A) 申请公布日期 1968.07.10
申请号 GB19660018462 申请日期 1966.04.27
申请人 MERCK & CO. INC. 发明人
分类号 C07C63/70;C07C63/72;C07C65/30;C07D303/04 主分类号 C07C63/70
代理机构 代理人
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