METHOD OF MAKING CARBOXYLATED CELLULOSE FIBERS AND PRODUCTS OF THE METHOD

摘要

The invention is directed to a method of making carboxylated cellulose fiber s whose fiber strength and degree of polymerization is not significantly sacrificed. The method involves the use of cyclic nitroxide free radical compounds as a primary oxidant and a hypohalite salt as a secondary oxidant in an aqueous environment. Preferably the oxidized cellulose is then stabilized against D.P. loss in alkaline environments and color reversion with a reduci ng agent such as sodium borohydride. Alternatively it may be treated with an oxidant such as sodium chlorite. The method results in a high percentage of carboxyl groups located at the fiber surface. The product is especially usef ul as a papermaking fiber where it contributes strength and has a higher attraction for cationic additives. The product is also useful as an additive to recycled fiber to increase strength. The method can be used to improve properties of either virgin or recycled fiber. It does not require high .alpha.-cellulose fiber but is suitable for regular market pulps.