发明名称 |
PHOSPHORYLATED POLY(STYRENE-CO-DIVINYLBENZENE)-BASED CHELATE RESIN FOR ADSORPTION OF HEAVY METAL IONS, AND PREPARING METHOD THEREOF |
摘要 |
PURPOSE: Provided is a phosphorylated poly(styrene-co-divinylbenzene)-based chelate resin which is excellent in chelate adsorption power to a certain heavy metal ion, and a preparing method thereof. CONSTITUTION: The phosphorylated poly(styrene-co-divinylbenzene)-based chelate resin is represented by the formula 1, wherein a spacer of an ethylene benzyl sulfone linkage structure is introduced onto a phenyl ring, and successively, a phosphono functional group is introduced thereonto, and is prepared by the method comprising the steps of: reacting a phenyl ring in a spherical copolymer resin of styrene and divinylbenzene, with chloromethyl, followed by thiolating with thiourea/aqueous alkali solution to prepare a thiol group-containing copolymer resin of the formula 2; reacting the obtained copolymer resin with chloroethanol to convert into a hydroxyethyl benzyl thioether group, followed by chlorination to prepare a chloroethyl benzyl thioether linkage structure-containing copolymer resin of the formula 3; and reacting the obtained copolymer resin with triethylphosphite/aqueous alkali solution. In the formula 1-3, A represents a hydrogen atom or an alkali metal atom.
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申请公布号 |
KR20050024759(A) |
申请公布日期 |
2005.03.11 |
申请号 |
KR20030060864 |
申请日期 |
2003.09.01 |
申请人 |
AEKYUNG SPECIALTY CHEMICALS CO., LTD.;KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY |
发明人 |
BANG, YOUNG GIL;KIM, KYUNG MAN;PARK, IN HWAN |
分类号 |
C08G61/02;(IPC1-7):C08G61/02 |
主分类号 |
C08G61/02 |
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