摘要 |
1,208,277. Production of esters. IMPERIAL CHEMICAL INDUSTRIES Ltd. 23 April, 1968 [9 May, 1967], No. 21436/67. Heading C2C. A process for the production of glycol esters of dicarboxylic acids comprises reacting in an organic solvent an olefine oxide, a dicarboxylic acid in the presence of ammonia or an ammonium salt of a carboxylic acid. In the examples bis-(#-hydroxyethyl)-terephthalate is prepared by reacting terephthalic acid with ethylene oxide in the presence of ammonium terephthalate as catalyst. |