发明名称 Processes for preparation of cyclopropylethanol, cyclo-propylacetonitrile and intermediates of both
摘要 A process for preparation of cyclopropylethanol, which comprises subjecting a 3-cyclopropyl-2,3-epoxypropionic acid ester to solvolysis, treating the product of the solvolysis with an acid to obtain cyclopropylacetaldehyde, and reducing the obtained cyclopropylacetaldehyde; and a process for preparation of cyclopropylacetonitrile, which comprises subjecting a 3-cyclopropyl-2,3-epoxypropionic acid ester to solvolysis in the presence of a base, treating the product of the solvolysis with an acid to obtain cyclopropylacetaldehyde, reacting the obtained cyclopropylacetaldehyde with hydroxylamine or salts thereof to obtain cyclopropaneacetaldehyde oxime, and reacting the obtained cyclopropaneacetaldehyde oxime with acetic anhydride. According to the present invention, cyclopropylethanol and cyclopropylacetonitrile can be prepared at low costs and industrially advantageously.
申请公布号 US2005020846(A1) 申请公布日期 2005.01.27
申请号 US20040493224 申请日期 2004.05.06
申请人 UJITA KATSUJI 发明人 UJITA KATSUJI
分类号 C07C29/14;C07C45/58;C07C249/08;C07C251/38;C07C253/00;C07C255/31;(IPC1-7):C07C255/31 主分类号 C07C29/14
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