发明名称 PHOSPHOLANE SALTS AND THEIR USE IN ENANTIOSELECTIVE HYDROGENATION
摘要 Process for preparing a catalyst solution by reacting metal complexes and diphosphines in the presence of an inert organic solvent, which is characterized in that a) an uncharged or cationic metal complex having a TM8 metal as central atom, and b) a salt of a chiral ditertiary diphosphine which has one or two phospholane groups which are bound to a carbon chain having from 2 to 4 carbon atoms and contain anions selected from the group consisting of RCCOO<->, RCSO3<->, BF4<->, PF6<->, AsF6<->, SbF6<->, B(C6F5)4<-> and B(3,5-bistrifluoromethylphenyt)4<->, are reacted with one another, where the ratio of the components a) and b) is from 1 : 1 to 1 : 2 and RC is C1-C6-haloalkyl, C5-C10-­halocycloalkyl or C6-C10-haloaryl.
申请公布号 WO2004098772(A3) 申请公布日期 2005.01.20
申请号 WO2004EP50732 申请日期 2004.05.07
申请人 SOLVIAS AG;KESSELGRUBER, MARTIN;THOMMEN, MARC 发明人 KESSELGRUBER, MARTIN;THOMMEN, MARC
分类号 C07F9/6574 主分类号 C07F9/6574
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