摘要 |
The hyperbranched polymers are at least one anhydrosugar-related compound selected from the dianhydrosugar alcohol [1]: (wherein R is hydrogen atom or a hydrocarbon group having from 1 to 30 carbon atoms, provided that nR's are equal to or different from one another and at least one R of nR's is hydrogen atom, and symbol n is an integer from 1 to 10) and the anhydrosugar alcohol [2]: (wherein each of R1, R2, R3 and R4 is hydrogen atom or a hydrocarbon group having from 1 to 30 carbon atoms; provided that R1, mR2's, pR3's and R4 are equal to or different from one another and at least one R2 or R3 of said mR2's and pR3's is hydrogen atom, respectively; and symbol m is zero (0) or an integer from 1 to 20 and symbol p is an integer from 1 to 20, provided that symbol m+p is an integer from 1 to 20) or at least one anhydrosugar-related compound selected from the dianhydrosugar alcohol [1] and/or the anhydrosugar alcohol [2] with at least one sugar compound selected from the anhydrosugar as represented by the general formula [3], [4], [5], [6] or [7]. The hyperbranched polymers are readily prepared by polymerizing the dianhydrosugar alcohol or the anhydrosugar [1] or [2] or the dianhydrosugar alcohol or the anhydrosugar [1] or [2] together with the anhydrosugar in the presence of a cationic or anionic initiator.
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