摘要 |
<p>The invention relates to a process for preparing 1-octene by reacting 1,3-butadiene with a telogen of the formula H-X-Y-H, where X is O, N, S or P and Y is C, N or Si and X and Y bear, depending on their valence, further substituents, in the presence of a telomerization catalyst to form a telomer of the formula H<SUB>2</SUB>C-CH-CH<SUB>2</SUB>-CH<SUB>2</SUB>-CH<SUB>2</SUB>-CH-CH-CH<SUB>2</SUB>-X-Y-H, partially hydrogenating the telomer to form a 1-substituted 2-octene of the formula H<SUB>3</SUB>C-CH<SUB>2</SUB>-CH<SUB>2</SUB>-CH<SUB>2</SUB>-CH<SUB>2</SUB>-CH-CH-CH<SUB>2</SUB>-X-Y-H and dissociating the 1-substituted 2-octene to give 1-octene.</p> |