PREPARATION OF HALOMETHYLBENZOYL CYANIDES AND NOVEL HALOMETHYLBENZOYL CYANIDES

摘要

12 A process for preparing halomethylbenzoyl cyanides I Ph-CO-CN I (Ph = phenyl radical substituted by chloromethyl or bromomethyl which, if desired, can additionally carry 1 - 4 further radicals) by reacting halomethylbenzoyl chlorides II Ph-CO-C1 II with an alkali metal cyanide or transition metal cyanide, if appropriate in an organic diluent, and novel halomethylbenzoyl cyanides I' (see formula I') (X = halogen, C1-C4-alkyl, C1-C4-alkoxy, CF3, C1-C5-alkyl-(C1-C5-alkyl)hydroxyimino or C1-C5-alkyl- (C2-C5-alkenyl)hydroxyimino; m = 0 to 4 and Y = chloromethyl or bromomethyl) are described. The halomethylbenzoyl cyanides I are important intermediates for the synthesis of plant protection agents.