| 摘要 |
2-Azolyl-cycloalkane-1,3-dione derivatives (I) are new. 2-Azolyl-cycloalkane-1,3-dione derivatives of formula (I), are new: Het = 5-membered nitrogen-containing heterocycle (optionally substituted (os) by halo, (halo)alkyl, (halo)alkoxy, (halo)alkenyloxy, CN, NO2, alkylthio, alkylsulfinyl, alkylsulfonyl, os phenyl or phenoxy), preferably triazolyl; m = 0 or 1; A = H; alkyl, alkenyl, (poly)alkoxyalkyl or alkylthioalkyl (all os by halo); os unsaturated cycloalkyl (in which at least one ring atom is optionally replaced by a heteroatom); or (hetero)aryl or aralkyl (all os by halo, (halo)alkyl, (halo)alkoxy, CN or NO2); A' = H or alkyl; or CAA' = os ring (in which at least one ring atom is optionally replaced by a heteroatom); or A + Q1 = os alkanediyl, in which two non-adjacent C-atoms may together form a further os ring; Q1 = H, (alkoxy)alkyl, os cycloalkyl (in which a ring CH2 is optionally replaced by O or S); or phenyl(alkyl) or heteroaryl(alkyl) (all os); Q2 - Q4 = H or alkyl; or CQ1Q2 = CAA'; G = H, -COR1, -C(L)-MR2, -SO2R3, -P(L)R4R5, E or -C(L)-NR6R7; E = metal or ammonium ion; L, M = O or S; R1 = alkyl(thioalkyl), alkenyl, alkoxyalkyl or polyalkoxyalkyl (all os by halo); cycloalkyl (os by halo, alkyl or alkoxy, and optionally interrupted by at least one heteroatom); or phenyl(alkyl), phenoxyalkyl or heteroaryl(oxyalkyl) (all os); R2 = (alkoxy)alkyl, alkenyl or polyalkoxyalkyl (all os by halo); or cycloalkyl, phenyl or benzyl (all os); R3 = (halo)alkyl, phenyl or benzyl (all os); R4, R5 = alkyl, alkoxy, mono- or dialkylamino, alkylthio, alkenylthio or cycloalkyl (all os by halo); or phenyl, benzyl, phenoxy or phenylthio (all os); and R6, R7 = H; (cyclo)alkyl, alkenyl or alkoxy(alkyl) (all os by halo); or phenyl or benzyl (both os); or NR6R7 = heterocycle (optionally interrupted by O or S). An Independent claim is also included for the preparation of (I). |
