POLYMER COMPOSITION AND PROCESS TO MANUFACTURE HIGH MOLECULAR WEIGHT-HIGH DENSITY POLYETHYLENE AND FILM THEREFROM

摘要

The present invention includes a multimodal polyethylene composition has (1) a density of at least about 0.940 g/cm3 as measured by ASTM Method D-1505; (2) a melt flow index (I5) of from about 0.2 to about 1.5 g/10 min (as measured by ASTM D-1238, measured at 190 ~C and 5 kilograms); (3) a melt flow index rati o (I21/I5) of from about 20 to about 50; (4) a molecular weight distribution, Mw/Mn, of from about 20 to about 40; (5) a bubble stability measured on specified equipment according to specified conditions for a film of about 6 X 10-6 m thickness of at least about 1.22 m/s line speed, at least about 45 kg/hr (0.013 kg/sec) output rate, or at least about 0.5 lb/hr/rpm (0.0000011 kg/s/rps) specific output rate or a combination thereof; the composition comprising; and (6) a dart impact on 12.5 micron (1.25 X 10-5 m) film of at least 300 g; measured according to ASTM 1709, Method A; (A) a high molecular weight fraction which; (a) is present in an amount of from about 30 to about 70 weight percent (based on the total weight of the composition); (b) has a density of at least about 0.860 g/cm3 as measured by ASTM D-1505; (c) has a melt flow index (I21) of from about 0.01 to about 50 g/10 min (as measured b y ASTM D-1238, measured at 190 ~C and 21.6 kilograms); and (d) a melt flow ind ex ratio (I21/I5) of from about 6 to about 12; and (B) a low molecular weight fraction which; (a) is present in an amount of from about 30 to about 70 weight percent (based on the total weight of the composition); (b) has a density of at least about 0.900 g/cm3 as measured by ASTM D-1505; (c) has a melt flow index (I2) of from about 0.5 to about 3000 g/10 min (as measured b y ASTM D-1238, measured at 190 ~C and 2.16 kilograms); (d) a melt flow index ratio (I21/I5) of from about 5 to about 15; and (e) is prepared using a mole ratio of alpha olefin to ethylene of less than or equal to about 0.001:1. Th e invention also includes a process for producing a multimodal ethylene polyme r, which process comprises the following steps: (1) contacting in a first gas phase fluidized bed reactor under polymerization conditions and at a temperature of from about 70 ~C to about 110 ~C, a supported titanium magnesium catalyst precursor, cocatalyst, and a gaseous composition, the gaseous composition having; (i) a mole ratio of alpha-olefin to ethylene of from about 0.01:1 to about 0.8:1; and optionally (ii) a mole ratio of hydrog en to ethylene of from about 0.001:1 to about 0.3:1, to produce a high molecula r weight polymer(HMW); and (2) transferring the HMW polymer from step 1 to a second gas phase fluidized bed reactor under polymerization conditions and a t a temperature of from about 70 ~C to about 110 ~C, with a gaseous compositio n having; (i) a mole ratio of alpha-olefin to ethylene of from about 0.0005:1 to about 0.01:1; and (ii) a mole ratio of hydrogen (if present) to ethylene of from about 0.01:1 to about 3:1 to form a polymer blend product; and (3) melting the polymer blend product in an extruder having a mixer vent wherein ; (ii) the mixture vent has an oxygen concentration of from about 0.05 to abou t 6 volume percent oxygen in nitrogen; and (ii) the extrusion temperature is sufficient to melt the polymer and achieve tailoring in the presence of oxygen; and (4) passing the molten polymer blend through one or more active screens, wherein in the 5 case of two or more active screens, the screens ar e positioned in series, each active screen having a micron retention size of from about 2 to about 70, at a mass flux of about 1.0 to about 20 kg/s/m2) t o form a screened molten polymer blend. The composition is preparable by the process and is preferably prepared by the process. The resin exhibits improv ed extrusion processing at high commercial line speeds, while exhibiting an excellent balance of 10 bubble stability, dart drop, and FAR, as well as outstanding NCLS with good flexural modulus.