发明名称 Method for producing dehydro rose oxide
摘要 The present invention relates to a method for producing dehydro rose oxide by reacting isoprenol and prenal in the presence of at least one sulfonic acid of formula R1—SO3H as catalyst, wherein R1 is selected from phenyl which carries 2 or 3 C1-C4-alkyl substituents, phenyl which carries one C8-C20-alkyl substituent and optionally also 1 or 2 C1-C4-alkyl substituents, and naphthyl which optionally carries 1 or 2 C1-C4-alkyl substituents.
申请公布号 US9346779(B2) 申请公布日期 2016.05.24
申请号 US201414889541 申请日期 2014.05.15
申请人 BASF SE 发明人 Schrems Marcus G.;Eggert Jan;Müller Jan U.;Arndt Jan-Dirk;Gottwald Günter;Hütt Volker
分类号 C07D309/04;C07D309/18;B01J31/02 主分类号 C07D309/04
代理机构 Drinker Biddle & Reath LLP 代理人 Drinker Biddle & Reath LLP
主权项 1. A method for producing 4-methylene-2-(2-methylprop-1-enyl)tetrahydropyran of formula Iwhich method comprises reacting 3-methylbut-3-en-1-ol of formula II and 3-methylbut-2-enal of formula IIIin the presence of at least one sulfonic acid catalyst of formula R1—SO3H, wherein R1 is selected from phenyl that includes 2 or 3 C1-C4-alkyl substituents, phenyl that includes one C8-C20-alkyl substituent and optionally 1 or 2 C1-C4-alkyl substituents, and naphthyl, which optionally includes 1 or 2 C1-C4-alkyl substituents.
地址 Ludwigshafen DE