| 摘要 |
A copolymer is new. A copolymer of formula (AB(DB)oA) is new. A : R1>, OR1>, or monovalent radical of formula R[NHabFc)-uR]g(NHdEeFf)-u1>u2X-> (II); u : (a+2b+c-1)+; u1>(d+2e+f-2)+; u2[g(a+2b+c-1)+d+2e+f-2]; R1>1H or 1-100C monovalent hydrocarbyl radical optionally interrupted by and/or substituted by Q and which optionally containing Q1; Q : N, O, P, B, Si, and/or S; Q1C(O), C(O)O, C(O)NR9> , NR9>, O, S, N, or triple boundN units, and optionally substituted by NR9>, OH, or SH; R : 1-50C divalent hydrocarbyl radical optionally interrupted by and optionally substituted by Q and which optionally contains C(O), C(O)O, C(O)NR9>, NR9>, O, S, or N units; R9>H or 1-18C monovalent hydrocarbyl optionally interrupted by Q and optionally substituted by OH and/or SH; a-c : 0-2; a+b+c : 1 or 2; d-f : 0-3; d+e+f : 2 or 3; g : 0-10; E : radical of formula (R2>NR3>3+); R2>1-10C divalent hydrocarbyl radical optionally interrupted by and optionally substituted by Q, optionally containing Q1, or optionally substituted by NR9>, OH, or SH; R3>1-20C monovalent hydrocarbyl radical optionally interrupted by and optionally substituted by Q, optionally containing Q1, or substituted by NR9>, OH, and/or SH groups; X->organic or inorganic anion; F : radical of formula CH2CHRC(O)G(R2G)h[CH2CH2O]i[C3H6O]j[(CH2)4O]k(R2G)hR5 or CH2CH(OH)CH2G(R2>G)h[CH2CH2O]i[C3H6O]j[(CH2)4O]k(R2>G)h; R4>H or Me; R5>hydrogen atom, a 1-10C monovalent hydrocarbyl radical, or unit consisting of CH2CR4>C(O), (R1>)2NCH2CHR4>C(O), R4>CH2C(O), HOCH2CH(OH)CH2, or methyl oxirane; G : divalent group O or NR9>; h : 0 or 1; i-k : 0-200;B=divalent radical comprising units of formula (SiR6>2O2/2)l, (SiR6>R7>)2/2)m, (SiR6>2)p+l, or (SiO3/2)2; R6>H, OR1>, or 1-200C monovalent alkyl optionally substituted by halo, carboxyl, epoxy, hydroxyl, or polyether groups, and optionally interrupted by C(O), C(O)O, C(O)NR9>, NR9>, O, or S; R7>monovalent radical of formula (II); l : 0-5000; p : 0-500; D : divalent radical of formula {[R(NHaEbFc]nJ[NHaEbFcR]n]-u3>u4X->; u3>,u4[2n(a+2b+c)-4]; n : 1-10; J : CH2CHR4>C(O)G(R4>G)h[CH2CH2O]i[C3H6O]j[(CH2)4 O]k(R2>G)hC(O)CHR4>CH2, or CH2CH(OH)CH2G(R2>G)h[CH2CH2O]i[C3H6]j[(CH2)4O]k(R2>G)hCH2CH(OH)CH2; o : >=0. The copolymer contains at least one E radical and one F radical. An independent claim is also included for preparing a copolymer (Q) by reacting organosilicon compounds or mixtures with polyethers and organic compounds. |
