摘要 |
The invention provides a process for production of methanol from a feed stream rich in hydrogen carbon monoxide and carbon dioxide. The feed stream is converted to a converted process stream comprising methanol and small amounts of higher alcohols, aldehydes and ketones in the presence of a catalyst active in conversion of hydrogen and carbon monoxide into methanol. The converted process stream is cooled to a cooled process stream to 20-200°C. The cooled process stream is hydrogenated into a hydrogen ated process stream rich in methanol and depleted in aldehydes and ketones in presence of a hydrogenation catalyst. The catalyst is active in conversion of aldehydes and ketones into alcohols in a process stream rich in methanol and further comprising hydrogen, carbon monoxide and carbon dioxide. The hydrogenated process stream is cooled to a cooled, condensed process stream, and subsequently the cooled, condensed process stream is separated into a gas phase and a liquid crude methanol phase. |
申请人 |
HALDOR TOPSOEE A/S;NIELSEN, POUL, ERIK, HOEJLUND;JORGENSEN, SUSANNE, LAEGSGAARD |
发明人 |
NIELSEN, POUL, ERIK, HOEJLUND;JORGENSEN, SUSANNE, LAEGSGAARD |