发明名称 |
PREPARATION METHOD OF DIPHENYL CARBONATE USING TIN COMPOUND COORDINATED WITH SULFURIC ACID DERIVATIVE AS CATALYST |
摘要 |
PURPOSE: A method for preparing diphenyl carbonate using a tin compound coordinated with a sulfuric acid derivative as a catalyst is provided, to obtain diphenyl carbonate used as a source material of polycarbonate with a high yield without side reaction in a wider temperature range within a short time. CONSTITUTION: The method comprises the step of reacting dimethyl carbonate and phenol in a catalyst which is an organic tin compound having a sulfuric acid derivative represented by the formula 1 as a ligand, wherein R is an alkyl group of C1-C6 or a phenyl group; R1 is a halogen atom, an alkyl group of C1-C6, a haloalkyl group of C1-C6 or a tolyl group; and n is 1 or 2. Preferably the content of the catalyst is 0.1-10 mol% based on the amount of dimethyl carbonate; the molar ratio of phenol to dimethyl carbonate is 2-20; reaction temperature is 130-250 deg.C; and the reaction time is 1-24 hours.
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申请公布号 |
KR20040061898(A) |
申请公布日期 |
2004.07.07 |
申请号 |
KR20020088200 |
申请日期 |
2002.12.31 |
申请人 |
KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY |
发明人 |
AHN, BYEONG SEONG;KIM, HONG GON;KIM, HUN SIK;LEE, HYEON JU |
分类号 |
C07C68/06;(IPC1-7):C07C68/06 |
主分类号 |
C07C68/06 |
代理机构 |
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