发明名称 |
Trihydrate of catena-[(µ2-O,O')-ethylenediamine tetraacetato)bismuthate(III)] of hexaaquacopper(II) in the capacity of catalyst in the water radiolysis process |
摘要 |
The invention relates to the chemistry of heterometallic coordinative compounds and radiochemistry and may be used in the capacity of water radiolytic decomposition catalyst. Summary of the invention consists in the utilization as catalyst of the trihydrate of catena -[(µ2-O,O')-ethylenediamine tetraacetato)bismuthate(III)] of hexaaquacopper(II){[Cu(H2O)6] [BiEdta]2.3H2O, where H4Edta=(HOOCCH2)2 N(CH2)2N(CH2COOH)2}. The hydrogen radiolytic yield in such case increases by 40,2 times in comparison with the uncatalyzed process and by 11,3 times in comparison with the analogue - the dimer of aquaethylenediamine tetraacetatobismuthate(III) of 1,2-dinitrotetraaminecobalt(III).Claims: 1Fig.: 2 |
申请公布号 |
MD2476(F1) |
申请公布日期 |
2004.06.30 |
申请号 |
MD20030000117 |
申请日期 |
2003.05.14 |
申请人 |
UNIVERSITATEA DE STAT DIN MOLDOVA |
发明人 |
GULEA AURELIAN;CECAL ALEXANDRU;PARASCHIVESCU ADRIAN;BULIMESTRU ION;WIGNACOURT JEAN-PIERRE;TAPCOV VICTOR |
分类号 |
B01J19/08;C01B3/04;C01G3/14;C07F1/08;(IPC1-7):B01J19/08;B01J2370;B01J2384;C07N22907;C07N21501;C07N5524;C07N47/56;C01G2900 |
主分类号 |
B01J19/08 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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