SELF-HEALING ORGANOSILOXANE MATERIALS CONTAINING REVERSIBLE AND ENERGY-DISPERSIVE CROSSLINKING DOMAINS
摘要
Self-healing copolymeric materials comprising a plurality of intermediate strength crosslinks are provided. The copolymeric materials comprise a silicon component and a plurality of crosslinking components. The crosslinking components comprise a polymeric structure forming a structure held together by ionic and/or hydrogen bonding with a net intermediate strength. The plurality of intermediate strength crosslinks provide toughness to the material, and allow for rehealing by allowing reforming of the crosslinks after a disruptive stress incidence. The material is also suited for recasting, and can be used as an active matrix by incorporating additional substances. Articles of manufacture incorporating such materials, and methods of recasting such materials are also provided.