发明名称 |
Recovery of isophoronediamine, useful in production of e.g. polyurethanes, comprises distillation of the crude diamine into a fraction having a cis/trans ratio of greater than 73/27 and a fraction having a cis/trans ratio of less than 66/34 |
摘要 |
Recovery of isophoronediamine (IPDA) comprises preparation of IPDA having a cis/trans isomer ratio of less than 73/27 and separation into at least 5 fractions by distillation including an IPDA fraction having a cis/trans ratio of greater than 73/27 and a fraction having a cis/trans ratio of less than 66/34. A process for the recovery of 3-aminomethyl-3,5,5-trimethylcyclohexylamine (isophoronediamine, IPDA) comprises; (a) preparation of IPDA having a cis/trans isomer ratio of less than 73/27; (b) introduction of IPDA to the middle region of a distillation column having inserts and distillation of IPDA at 5-300 degreesC and 10-2000 mbar; (c) optionally further purification of the IPDA from (b) by distillation in at least one further column whereby the IPDA from step (b) and (c) are separated into at least 5 fractions comprising an organic fraction (1a) containing impurities having a lower b. pt. than trans-IPDA, an aqueous fraction (1b) containing impurities having a lower b. pt. than trans-IPDA, a fraction (2) containing impurities having a higher b. pt. than cis-IPDA, an IPDA fraction (3) having a cis/trans ratio of greater than 73/27 and an IPDA fraction (4) having a cis/trans ratio of less than 66/34.
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申请公布号 |
DE10236674(A1) |
申请公布日期 |
2004.02.19 |
申请号 |
DE2002136674 |
申请日期 |
2002.08.09 |
申请人 |
BASF AG |
发明人 |
FUNKE, FRANK;HILL, THOMAS;WATZDORF, JOBST RUEDIGER VON;MATTMANN, WOLFGANG;HARDER, WOLFGANG;HENKES, ERHARD;LITTMANN, GERD;JULIUS, MANFRED |
分类号 |
C07C209/86;B01D3/14;C07C209/84;C07C211/36;(IPC1-7):C07C209/82;B01D3/00 |
主分类号 |
C07C209/86 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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