发明名称 COMPLEX CATALYST, PROCESS FOR PRODUCING THE COMPLEX CATALYST, AND PROCESS FOR PRODUCING ALCOHOL DERIVATIVE WITH THE COMPLEX CATALYST
摘要 <p>There are provided (asymmetric) complex catalysts comprising metal complexes and Lewis acids as components, the metal complex being of formula (1): &lt;CHEM&gt; wherein R&lt;1&gt;, R&lt;2&gt;, R&lt;3&gt;, R&lt;4&gt;, R&lt;5&gt;, R&lt;6&gt;, R&lt;7&gt; and R&lt;8&gt; are the same or different and are independently hydrogen, halogen, alkyl or the like; one of R&lt;9&gt; and R&lt;10&gt; is hydrogen and the other is alkyl of 1 to 4 carbon atoms or the like; Q is a single bond or alkylene of 1 to 4 carbon atoms; M is a metal ion; and A is a balancing counter ion or ligand; processes for the production of these complex catalysts; processes for the production of (optically active) alcohol derivatives, characterized in that cyclic ether compounds are reacted with phenol derivatives in the presence of these complex catalysts; and further processes for producing (optically active) nitrogen-containing heterocyclic compounds by reacting these alcohol derivatives with halogenated nitrogen-containing heterocyclic compounds in the presence of a base.</p>
申请公布号 EP1380342(A1) 申请公布日期 2004.01.14
申请号 EP20020720443 申请日期 2002.04.17
申请人 SUMITOMO CHEMICAL COMPANY LIMITED 发明人 SASAKI, KAZUAKI
分类号 B01J31/18;B01J31/22;C07D213/64;(IPC1-7):B01J31/22;C07B53/00;B01J27/20;C07C43/23;C07C41/03 主分类号 B01J31/18
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