发明名称 Recover and recycle rhodium from spent partial oxidation catalysts
摘要 A method for the recovery of rhodium from spent supported catalysts. In one embodiment, a method for recovering rhodium from a host material includes roasting the host material in air at a temperature sufficient to convert at least a portion of rhodium to Rh2O3, leaching the host material in a solution with a leaching constituent which is reactive with Rh2O3 to form a first intermediate species, reacting the first intermediate species in a solution with an acidifying constituent or complexing agent to form a second intermediate species, and purifying the second intermediate species. Preferably, the roasting temperature is approximately from 600° C. to 800° C. for 0.5 to 10 hours. In some embodiments, the host material is ground to particles in the range of 0.1 to 10 mm.
申请公布号 US2003236440(A1) 申请公布日期 2003.12.25
申请号 US20020176224 申请日期 2002.06.20
申请人 CONOCO INC. 发明人 CHEN ZHEN;RICKETSON KEVIN L.;HU BAILI;WRIGHT HAROLD A.;ALLISON JOE D.
分类号 B01J20/34;C01B3/26;C01B3/38;C01G55/00;C22B3/10;C22B11/00;C22B11/02;(IPC1-7):C22B11/00;C07C27/00 主分类号 B01J20/34
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