发明名称 Plasma jet surface treatment of articles or coatings comprising crosslinked silicone used for, e.g. automobile air bags to increase surface energy and improve glue adhesion
摘要 A method of surface treating an article comprising crosslinked silicone by plasma jet using a homogeneous atmospheric plasma generated by a plasma projection equipment comprising a rotating head comprising one or more plasma nozzles eccentric with respect to the axis of rotation and each capable of generating a plasma jet with an axis parallel to the axis of rotation. The crosslinked silicone is a polyorganosiloxane (POS) crosslinked by polyaddition of -SiH groups onto -Si-alkenyl (preferably vinyl) groups in a silicone preparation comprising: (1) one or more POS with -Si-alkenyl (vinyl) groups; (2) one or more POS with -SiH groups; (3) one or more metallic (preferably platinum) catalysts; (4) optionally one or more POS resins bearing -Si-alkenyl groups; (5) optionally a crosslinking inhibitor; (6) optionally one or more adhesion promoters; (7) optionally one or more mineral fillers; and (8) optionally one or more functional additives to give specific properties. It is disclosed that the equipment used to carry out the treatment is described in US-B-6265690 and is commercially available under the name Plasma Treat (RTM). Independent claims are included for (1) a means of producing an crosslinked silicone article treated by the claimed method by forming a silicone element from the liquid silicone preparation above, crosslinking, surface treating at least part of the surface of the crosslinked element and repeating the first two steps, (2) a method of assembling the crosslinked silicone articles by applying a liquid glue to one or more surfaces, (3) a crosslinked silicone elastomer coating obtainable by the claimed method which has an adhesion force measured by a peel test of 2.7 N/cm, more preferably 2.8 N/cm and most preferably 3-10 N/cm.
申请公布号 FR2840826(A1) 申请公布日期 2003.12.19
申请号 FR20020007443 申请日期 2002.06.17
申请人 RHODIA CHIMIE 发明人
分类号 B05D3/04;B05D5/10;B05D7/02;B05D7/26;B29C33/40;B29C59/00;B29C59/14;B29C65/52;B29K83/00;C08J5/12;C08J7/00;C08J7/18;C08K3/00;C08K5/05;C08K5/5425;C08L83/02;C08L83/05;C08L83/07;C09D183/04;C09D183/05;C09D183/07;C09J5/02 主分类号 B05D3/04
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