发明名称 Method of evaluating the catalytic activity of a rare earth alkoxide
摘要 This invention provides a method of evaluating the catalytic activity of a rare earth alkoxide used as a starting material of a basic catalyst or an asymmetric synthesis catalyst. The rare earth alkoxide used as the subject of evaluation and 2,2'-dihydroxy-1,1'-binaphthol are used as the starting material to prepare a rare earth complex catalyst which is then used to conduct the asymmetric epoxidation of an enone. The epoxy enone formed by this reaction, the unreacted enone, and the enantiomeric excess are measured, and from these results, the catalytic activity of the rare earth alkoxide is evaluated.
申请公布号 US2003228698(A1) 申请公布日期 2003.12.11
申请号 US20030431225 申请日期 2003.05.07
申请人 KUBOSHIMA YOSHINORI;MATSUNAGA SHIGEKI;SHIBASAKI MASAKATSU 发明人 KUBOSHIMA YOSHINORI;MATSUNAGA SHIGEKI;SHIBASAKI MASAKATSU
分类号 B01J31/22;C07D303/32;G01N31/10;(IPC1-7):G01N31/10 主分类号 B01J31/22
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