Crystalline ceric oxide sol and process for producing the same

摘要

There is provided a crystalline ceric oxide sol that is approximately monodisperse, and a process for producing the sol. A sol comprising crystalline ceric oxide particles, in which the particles have particle size I (particle size converted from a specific surface area by gas adsorption method) ranging from 10 nm to 200 nm and a ratio of particle size II (particle size measured by dynamic light scattering method) to the particle size I ranging from 2 to 6. The sol is prepared by reacting a cerium (III) salt with an alkaline substance in an aqueous medium under an inert gas atmosphere to give a suspension of cerium (III) hydroxide, and immediately blowing oxygen or a gas containing oxygen into the suspension to give a sol comprising crystalline ceric oxide particles, and wet-grinding the resulting sol. The sol is also prepared by calcining cerium carbonate at a temperature of 300 to 1100 DEG C to give crystalline cerium oxide particles, and wet-grinding the resulting particles.