发明名称 METHOD FOR ELECTROCHEMICAL PRODUCTION OF NI(0) PHOSPHITE AND DIPHOSPHITE COMPLEXES
摘要 Method for electrochemical production of phosphite and diphosphite Ni(0) complexes in a diaphragmless electrolyzer, containing an anode and cathode, by anode dissolution of metallic nickel in an aprotic solvent with subsequent electroreduction of nickel ions on the cathode with low hydrogen overvoltage in the presence of, for example, an equimolar amount, of phosphorus ligands, using direct or alternating current. The complexes are useful as catalysts.
申请公布号 PL353637(A1) 申请公布日期 2003.12.01
申请号 PL20000353637 申请日期 2000.08.17
申请人 E.I.DU PONT DE NEMOURS & CO. 发明人 STEPANOV ANDREI ALEKSANDROVICH;GRINBERG VITALI ARKAD'EVICH;JACKSON SCOTT CHRISTOPHER;LUNDGREN CYNTHIA ANNE;KULOVA TAT'JANA L'VOVNA
分类号 B01J31/22;B01J31/18;B01J37/34;C07F15/04;C25B3/00;C25B3/12 主分类号 B01J31/22
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