发明名称 |
ELEKTRONENAKZEPTORZUSAMMENSETZUNGEN AUF POLYMERMATRIZEN UND KATALYTISCHE HERSTELLUNG VON WASSERSTOFFPEROXID |
摘要 |
<p>A catalytic process for producing hydrogen peroxide from oxygen and hydrogen comprising the steps of: A) treating an aqueous suspension of heterogeneous catalyst with a source of oxygen and a source of hydrogen; B) separating the catalyst; and, C) isolating the produced hydrogen peroxide, wherein said catalyst is a complex of the formula: <CHEM> wherein each of Y<1>, Y<2>, and Y<3>, independently of the other, is phosphorus or arsenic; Z is a divalent group which reversibly forms a stable reduced form, said group containing two conjugated cationic centers which together have a negative E<o>red value; Me<2> is a trivalent or tetravalent metal of Group III, IVA, or IVB having an atomic number of at least 21 or a lanthanide; X is anion; n has a value of from 0 to 0.8; and p has a value of 1, 2 or 3; and R<3> is a nonreducible capping group.</p> |
申请公布号 |
DE69531903(D1) |
申请公布日期 |
2003.11.13 |
申请号 |
DE1995631903 |
申请日期 |
1995.12.27 |
申请人 |
THE TRUSTEES OF PRINCETON UNIVERSITY, PRINCETON;THOMPSON, MARK E.;SNOVER, JONATHAN LEE;JOSHI, VIJAY;VERMEULEN, LORI ANN;TANG, XIAOZHANG |
发明人 |
THOMPSON, E.;SNOVER, LEE;JOSHI, VIJAY;VERMEULEN, ANN;TANG, XIAOZHANG |
分类号 |
C07F7/00;B01J21/08;B01J23/40;B01J23/42;B01J29/04;B01J31/02;B01J31/16;B01J31/18;B01J35/00;B01J37/02;C01B3/04;C01B15/029;C07C2/00;C07F9/58;C08F8/40;C08F8/44;C08F30/02;C08F30/04;C08F230/02;C08F230/04;(IPC1-7):C01B15/00;B01J29/03 |
主分类号 |
C07F7/00 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|