发明名称 |
Kontinuierliches Verfahren zur Herstellung von Polyvinylacetat zum Herstellen von Polyvinylalkohol |
摘要 |
An improved process for the continuous production of poly(vinyl alcohol) which involves purifying poly(vinyl acetate) paste exiting from a polymerization reactor and dissolving the substantially pure poly(vinyl acetate) in a hydrolytic alcohol-containing solvent for subsequent saponification to produce poly(vinyl alcohol). Poly(vinyl acetate) paste, containing poly(vinyl acetate), vinyl acetate, and solvent, is heated to a temperature above the glass transition temperature but below a temperature which will degrade the poly(vinyl acetate) and is fed into a flashing area of an extruding devolatilization device. Vinyl acetate and solvent are flashed through vent ports in the flashing area of the devolatilization device and can then be recycled to a polymerization reactor, if desired. A substantially pure poly(vinyl acetate) melt, exiting the flashing area, is conveyed to a mixing area of the devolatilization device where it is mixed with a hydrolytic alcohol-containing solvent to form a solution for subsequent processing in a saponification unit. |
申请公布号 |
DE69905208(T2) |
申请公布日期 |
2003.11.13 |
申请号 |
DE1999605208T |
申请日期 |
1999.03.08 |
申请人 |
CELANESE INTERNATIONAL CORP., DALLAS |
发明人 |
WEBB, STEPHEN CHARLES;NANGERONI, JAMES FRANCIS;CARVILL, BRIAN THOMAS;FREY, BETH ANN |
分类号 |
C08F6/06;C08F8/12;C08F16/06;(IPC1-7):C08F8/12 |
主分类号 |
C08F6/06 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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