发明名称 METHOD FOR OXIDIZING ALCOHOL BY USING SULFUR-CONTAINING COMPOUND
摘要 PROBLEM TO BE SOLVED: To develop a method for carrying out oxidation of an alcohol, such as Swern oxidation and Corey-Kim oxidation without worrying about irritating odor and unpleasant odor. SOLUTION: This method for oxidizing the alcohol compound involves bringing the alcohol compound into contact with a sulfoxide compound represented by formula [1] (wherein, R<SP>1</SP>is a hydrocarbon group having≥7 total number of carbons at a linear carbon bond part obtained by not counting the number of carbons at branched parts and counting the number of carbons at the shortest part in a cyclic part; R<SP>2</SP>is an alkyl group, an aryl group or an aralkyl group), or a sulfide compound represented by the formula [2]: R<SP>1</SP>-S-R<SP>2</SP>(wherein, R<SP>1</SP>and R<SP>2</SP>are the same as the above). The method for producing a corresponding carbonyl compound by utilizing the oxidation reaction of the alcohol compound is also provided. COPYRIGHT: (C)2004,JPO
申请公布号 JP2003313151(A) 申请公布日期 2003.11.06
申请号 JP20020120167 申请日期 2002.04.23
申请人 WAKO PURE CHEM IND LTD;NOIDE MANABU 发明人 NOIDE MANABU;NISHIDE KIYOJI;OSUGI SHINICHI
分类号 C07C45/29;C07B61/00;C07C47/21;C07C47/238;C07C47/445;C07C47/55;C07C49/04;C07C49/437;C07C49/784;C07C49/786;(IPC1-7):C07C45/29 主分类号 C07C45/29
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