发明名称 METHOD FOR PRODUCING OPTICALLY ACTIVE 2-ACYLATED 1,2-DIOL COMPOUND DERIVATIVE
摘要 PROBLEM TO BE SOLVED: To develop a method for producing an optically active 1,2-diol compound in a high yield by optically resolving a (dl)-1,2-diol compound by a simple method without caring about purity of a raw material. SOLUTION: The (dl)-1,2-diol compound is reacted with a carboxylic halide compound in the presence of an optically active oxazoline-copper complex catalyst represented by formula (I) (R<SP>1</SP>s are each independently a 1<SP>-</SP>5C alkyl group, phenyl group or benzyl group) and a base to optically resolve the (dl)-1,2- diol compound. COPYRIGHT: (C)2004,JPO
申请公布号 JP2003313153(A) 申请公布日期 2003.11.06
申请号 JP20020117057 申请日期 2002.04.19
申请人 TOKUYAMA CORP 发明人 MATSUMURA ISAHIRO;MAKI HIDETOSHI;ONOMURA OSAMU;MURAKAMI SACHIE
分类号 C07C67/14;C07B53/00;C07B61/00;C07C67/56;C07C69/78;(IPC1-7):C07C67/14 主分类号 C07C67/14
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