摘要 |
PROBLEM TO BE SOLVED: To provide a phosphonodihydropyran derivative useful as pharmaceuticals, agrochemicals and their intermediates. SOLUTION: The phosphonodihydropyran derivative of formula (3) (R<SP>1</SP>and R<SP>2</SP>are H, a 1-6C alkyl or a 6-10C aromatic group; R<SP>3</SP>is a 1-4C alkyl; R<SP>4</SP>, R<SP>5</SP>, R<SP>6</SP>and R<SP>7</SP>are each H, a 1-6C alkyl, a 1-4C alkoxy, a 1-6C alkylthio, an arylthio or a 6-10C aromatic group; and R<SP>4</SP>and R<SP>6</SP>and/or R<SP>5</SP>and R<SP>7</SP>may together form X-CR<SP>10</SP>R<SP>11</SP>-CR<SP>12</SP>R<SP>13</SP>-CR<SP>14</SP>R<SP>15</SP>is produced by reacting a phosphonoacrolein derivative of formula (1) (the definitions of R<SP>1</SP>to R<SP>3</SP>are the same as those described above) with an olefin compound of formula (2) (the definitions of R<SP>4</SP>to R<SP>7</SP>are the same as those described above). COPYRIGHT: (C)2004,JPO
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