摘要 |
<p>The present invention is drawn to ink-jet ink compositions, methods, and systems for increasing the bleed and smear fastness and optical density of a printed image. Specifically, an aqueous ink-jettable ink composition is disclosed which exhibits a decrease in pH upon exposure to radiation, followed by precipitation of the ink colorant. The composition can comprise an ink vehicle, an effective amount of an ink colorant having pH dependent solubility properties, and an effective amount of a photo-initiated acid generator. The method comprises the steps of formulating the composition, jetting the ink composition from an ink-jet pen onto a substrate, and exposing the ink-jetted ink on the substrate to radiation wherein the ink-jet ink composition exhibits reduced pH, followed by precipitation of the colorant. Additionally, the system can comprise an ink-jet ink pen containing the ink-jettable ink composition, a substrate configured for accepting a printed image from the ink-jet pen, and an energy source configured for irradiating the printed image such that a decrease in pH is realized resulting in precipitation of the ink colorant.</p> |