| 摘要 |
FIELD: chemical technology. SUBSTANCE: invention relates to catalysts and methods for preparing nitrous oxide (N2O) by oxidation of ammonia with oxygen or oxygen- containing gas. Invention describes a catalyst and method for preparing nitrous oxide by oxidation of ammonia with oxygen or oxygen-containing gag that involves manganese- -containing active component applied on alumooxide carrier. Catalyst comprises the composition as an active component representing mixed amorphous oxide phase of the following non-stoichiometric composite: MnRxOy (0.05 <= x <= 2.24; 2.08 <= y <= 5.36) wherein R is bismuth and/or lanthanide, or mixture of amorphous phase of the composite: MnRxOy and crystalline manganese-containing phase. Invention relates also to the process for preparing nitrous oxide by oxidation of ammonia with oxygen or oxygen-containing gas that is carried out in the presence of manganese-containing catalyst of the above said composite at temperature 250-450 C. Invention provides preparing active catalyst showing selectivity with respect to nitrous oxide with reduced content of active component. Nitrous oxide is used widely in different branched on industry: in semiconductive, perfume, medicinal and food industries. EFFECT: improved preparing method, valuable properties of catalyst . 5 cl, 1 tbl, 10 ex
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