发明名称 A METHOD FOR THE PREPARATION OF CARBOXYLIC ACIDS BY HYDROXYCARBONYLATION IN THE PRESENCE OF PALLADIUM
摘要 The invention concerns a method for preparing beta, gamma saturated or unsaturated carboxylic acids. More particularly, the invention concerns hydroxycarbonylation of an organic compound comprising a conjugated unsaturation, such as butadiene, through the action of carbon monoxide and water in the presence of a palladium catalyst. The resulting carboxylic acids are preferably pentenoic acids. The invention is characterised in that the reaction medium at the end of the hydroxycarbonylation step is treated with hydrogen to reduce the palladium present in palladium 2+ oxidation state to zero oxidation state and to recover the precipitated palladium.
申请公布号 UA73622(C2) 申请公布日期 2003.09.15
申请号 UA20030065927 申请日期 2001.12.21
申请人 RHODIA POLYAMIDE INTERMEDIATES 发明人
分类号 C07B61/00;C07C51/14;C07C53/126;C07C57/03;(IPC1-7):C07C51/14 主分类号 C07B61/00
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