发明名称 |
Two phase preparation of carboxylic acid esters |
摘要 |
The methyl and ethyl esters of trifluoroacetic acid or chlorodifluoroacetic acid can be prepared in a technically simple manner from the corresponding acid chlorides and methanol or ethanol, respectively, in the presence of an "onium" salt of the acid as a catalyst. The alcohol is used in a stoichiometric excess, namely the molar ratio of alcohol to acid chloride is selected such that operation is in the region of a two-phase reaction. One of the phases is formed by the desired ester product, which is obtained in a high purity without any distillation.
|
申请公布号 |
US6583313(B1) |
申请公布日期 |
2003.06.24 |
申请号 |
US19980113547 |
申请日期 |
1998.07.10 |
申请人 |
SOLVAY FLUOR UND DERIVATE GMBH |
发明人 |
BRAUN MAX;EICHHOLZ KERSTIN;RUDOLPH WERNER |
分类号 |
B01J31/02;C07C67/14;C07C69/63;(IPC1-7):C07C67/08 |
主分类号 |
B01J31/02 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|