发明名称 SEPARATION OF REACTION PRODUCTS CONTAINING ORGANOPHOSPHORUS COMPLEXES.
摘要 This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organosphosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.
申请公布号 MXPA02009086(A) 申请公布日期 2003.05.23
申请号 MX2002PA09086 申请日期 2001.03.14
申请人 UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION 发明人 BRYANT, DAVID, ROBERT
分类号 B01D11/04;B01J23/46;B01J31/18;B01J31/24;B01J31/40;B01J38/00;C07B61/00;C07B63/00;C07C45/50;C07C45/80;C07C47/19;C07F9/02 主分类号 B01D11/04
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