发明名称 |
PREPARATION METHOD OF POLYISOIMIDE |
摘要 |
PURPOSE: A method for preparing polyisoimide is provided, to improve the mechanical properties, the heat stability, the electric insulation property, the flame retardancy and the chemical resistance by preventing the gelation generated during the cyclodehydration. CONSTITUTION: The method comprises the steps of polymerizing a dianhydride monomer and a diamine monomer; and preparing the polyisoimide from the polymer by the cyclodehydration in the presence of an end-capper selected from an acid chloride and a chloroalkylsilane at a low temperature of -30 to 10 deg.C. Preferably the acid chloride is selected from the group consisting of acetyl chloride, benzoic chloride, propanoic chloride and p-toluenesulfonyl chloride; and the chloroalkylsilane is chlorotrimethylsilane or chlorotriethylsilane. The amount of the end-capper is 0.01-0.2 mol based on 1 mol of the diamine monomer.
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申请公布号 |
KR20030027251(A) |
申请公布日期 |
2003.04.07 |
申请号 |
KR20010060355 |
申请日期 |
2001.09.28 |
申请人 |
KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY |
发明人 |
CHOI, GIL YEONG;HONG, YEONG TAEK;KIM, BYEONG HUI;KIM, JI HEUNG;KIM, JI SEOK;KIM, MUN SEON;KIM, YEONG JUN;LEE, BYEONG CHUN;WON, JONG CHAN |
分类号 |
C08G73/10;(IPC1-7):C08G73/10 |
主分类号 |
C08G73/10 |
代理机构 |
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