发明名称 IMPROVED SURFACE AREA OF COBALT CATALYST SUPPORTED BY SILICA CARRIER MATERIAL
摘要 The present invention teaches a method for increasing the cobalt surface area per gram of catalyst in a cobalt Fischer-Tropsch catalyst, supported on a silica-based carrier material, by using cobalt amine carbonate precursors. In accordance with a preferred embodiment, a Fischer-Tropsch catalyst includes a catalytically active first metal containing cobalt, and a carrier material containing silica or a silica compound with a cobalt surface area greater than 13 m2/g catalyst. The catalyst active in the FT reaction has a minimum alpha value of 0.87 and a CO conversion of 24 wt % or more. In accordance with another preferred embodiment, a process for producing a Fischer-Tropsch catalyst includes saturating silica or silica compounds with a solution of cobalt amine carbonate, removing the excess solution by filtration, heating the resulting product in order to allow cobalt hydroxycarbonate to precipitate, and drying and calcining the resulting product. Optionally the calcined product is reduced.
申请公布号 WO03024905(A1) 申请公布日期 2003.03.27
申请号 WO2002US30071 申请日期 2002.09.23
申请人 CONOCO INC. 发明人 JOTHIMURUGESAN, KANDASWAMY;ESPINOZA, RAFAEL, L.;SRINIVASAN, NITHYA
分类号 B01J21/08;B01J23/75;B01J23/89;B01J35/10;B01J37/02;B01J37/03;C10G2/00;(IPC1-7):C07C27/00;B01J23/00;B01J23/40;B01J23/58;B01J21/04 主分类号 B01J21/08
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