| 摘要 |
A method for efficiently separating pentafluoroethane (HFC-125) from a mixture thereof with chloropentafluoroethane (CFC-115). This method is performed by subjecting a mixture (2) of HFC-125 (6) and CFC-115 (4) to extractive distillation (1) to give highly concentrated HFC-125 (6). A hydrofluorocarbon compound (3) having two carbon atoms, particularly 1,1,1,2-tetrafluoroethane, is used as an extractant to obtain concentrated CFC-115 as a distillate and a mixture of HFC-125 having a reduced content of CFC-115 with the extractant as a bottom (5), the extractant being separated from HFC-124 in this mixture by distillation (9) and reused in the extractive distillation.
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