发明名称 PROCESS FOR THE PREPARATION OF ENANTIOMERICALLY PURE PYRETHROID INSECTICIDES
摘要 A process for producing compounds of formula (VIIa) and (VIIb) wherein X is a leaving group; Y and Y<1 >are idependently Cl or Br; and Z is Cl, Br or a haloalkyl group which process comprises a) reacting a compound of formula (VII) wherein X, Y, Y<1 >and Z are as defined for compounds (VIIa) and (VIIb) with a substantially optically pure chiral amine in a solvent to form a diastereoisomeric salt; b) separating the diastereomeric salt of each enantiomer; c) converting the diastereomeric salt of each anantiomer separately to compounds of formulae (VIIa) and (VIIb) respectively by acid or base hydrolysis, the use of the compounds in making pyrethroid insecticides and novel intermediates.
申请公布号 KR20030017639(A) 申请公布日期 2003.03.03
申请号 KR20037000695 申请日期 2003.01.17
申请人 发明人
分类号 A01N53/00;C07C51/487;A01N53/06;C07C51/09;C07C51/377;C07C51/41;C07C51/60;C07C55/32;C07C55/40;C07C61/15;C07C61/40;C07C67/14;C07C69/63;C07C69/74;C07C69/747 主分类号 A01N53/00
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