发明名称 Process of producing polytrimethylene terephthalate (PTT)
摘要 Process of producing polytrimethylene terephthalate (PTT) by esterification of terephthalic acid (TPA) with trimethylene glycol (TMG) in the presence of a catalytic titanium compound, precondensation and polycondensation. The esterification is effected in at least two stages, where in the first stage a molar ratio of TMG to TPA of 1.15 to 2.5, a content of titanium of 0 to 40 ppm, a temperature of 240 to 275° C., and a pressure of 1 to 5.0 bar, preferably 3.5 bar are used. In the at least one subsequent stage a content of titanium is adjusted which is higher than in the initial stage by 35 to 110 ppm.
申请公布号 US6512080(B2) 申请公布日期 2003.01.28
申请号 US20010860999 申请日期 2001.05.18
申请人 SHELL OIL COMPANY 发明人 KELSEY DONALD ROSS;BLACKBOURN ROBERT LAWRENCE;TOMASKOVIC ROBERT STEPHEN;REITZ HANS;SEIDEL ECKHARD;WILHELM FRITZ
分类号 C08G63/183;C08G63/78;C08G63/85;(IPC1-7):C08G63/78 主分类号 C08G63/183
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