| 摘要 |
A new polyhydroxyamide (A) for preparation of highly crosslinked, temperature stabile polymers, based on a benzenetricarboxylic acid to which side chains are bonded via an amide bond and which has terminal reactive groups through which highly crosslinked polymers can be obtained by direct polymerization. Polyhydroxyamides of formula (I): a, f, k = 0 or 1; b, g, l = 0-100; c, h, m = 0 or 1; d, i, n = 0 or 1; e, j, o = 0 or 1; and when a (f, k) = 0, b (g, l) = c (h,m) or = 0; when c (h, m) =o, d (i, n) = 0; when d (i, n) = 1, e (j, o) = 1, and when a (f, k) = 1 and b (g, l) = c (h, m) =0, d (i, n) = 0; Z = an up to 100C 4-bond residue; Y = a 2-bond residue with two carbonyl groups, which forms an amide bond with the adjacent nitrogen, which includes up to 100C atoms; and X = H or an up to 30C single bond residue with at least one reactive group which can form a bond with another reaction center. Independent claims are included for: (1) a three-dimensionally crosslinked polymer obtainable from a monomer, oligomer or polymer with at least one reactive group which can react with group X to form a chemical bond, by reaction with a polyhydroxyamide (A); and (2) a three-dimensionally crosslinked polymer in which the group X has a polymerizable double or triple bond, and the reactive group which can react with the group X to form a chemical bond is a polymerizable double or triple bond.
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