发明名称 METHOD OF OXIDIZING AN ALCOHOL USING A RECYCLABLE FLUOROUS SULFOXIDE
摘要 A method of oxidizing primary and secondary alcohols to an aldehyde or ketone using a fluorous sulfoxide or a fluorous sulfide is disclosed. The method includes regenerating and recycling the fluorous sulfoxide which has the structure, wherein Rf is fluorinated hydrocarbon chain containing one to twelve carbon atoms; R is C1-4alkyl or (CH2)n-Rf; and n is 1 to 3. These compounds are claimed per se.
申请公布号 WO03002526(A1) 申请公布日期 2003.01.09
申请号 WO2002US19274 申请日期 2002.06.18
申请人 THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS 发明人 CRICH, DAVID;NEELAMKAVIL, SANTHOSH
分类号 C07B39/00;C07C45/30;C07C205/44;C07C317/04;(IPC1-7):C07C317/04;C07C45/27 主分类号 C07B39/00
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