发明名称 |
Process for controlling the MWD of a broad or bimodal resin in a single reactor |
摘要 |
A process for controlling the MWD of a broad or bimodal resin in a single fluid bed reactor using a mixed catalyst composition containing a bimetallic catalyst and a make-up catalyst of at least one metallic component of the bimetallic catalyst. The bimetallic catalyst, which is formed with at least one metallocene of a transition metal, produces broad or bimodal molecular weight distribution polyolefin resin whose composition depends on the ratio of the concentration of the two catalyst components producing the HMW/LMW components. The make-up catalyst consisting of a single metal component is added in proportion necessary to make-up the deficiencies in the amount of the HMW/LMW component. The type of make-up catalyst added depends on whether increase of the HMW or LMW component produced by the bimetallic catalyst is sought. The mixed catalyst compostion may be fed into the reactor as a mixture or through separate catalyst ports of the reactor.
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申请公布号 |
US2002173601(A1) |
申请公布日期 |
2002.11.21 |
申请号 |
US20020142102 |
申请日期 |
2002.05.09 |
申请人 |
NOWLIN THOMAS E.;SCHREGENBERGER SANDRA D.;SHIRODKAR PRADEEP P.;TSIEN GRACE O. |
发明人 |
NOWLIN THOMAS E.;SCHREGENBERGER SANDRA D.;SHIRODKAR PRADEEP P.;TSIEN GRACE O. |
分类号 |
C08F4/642;B01J31/12;B01J31/14;B01J31/16;B01J31/22;C08F4/02;C08F4/60;C08F4/658;C08F4/659;C08F10/00;(IPC1-7):C08F4/44 |
主分类号 |
C08F4/642 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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