Carvone can be prepared by catalytic oxidation of limonene with 0.001-0.2 equivalent palladium or a salt thereof in the presence of a reoxidising agent such as a copper salt and a salt of a non-transition metal, for example sodium carbonate, in an organic solvent, the yield being improved if the oxidation is carried out in one step in the presence of oxygen and water. The presence of an acid results in a further improvement.
申请公布号
WO9912880(A9)
申请公布日期
2002.11.21
申请号
WO1998NL00505
申请日期
1998.09.04
申请人
NATIONALE AAN- EN VERKOOPCOOEPERATIE VOOR LAND -EN;MULDER, PATRICIUS, PETRUS, JOHANNES;VAN HAVEREN, JACCO;NIJHUIS, HERMAN, HENK