摘要 |
A thin film comprising a pyrochlore represented by the formula:wherein x is from about 0.45 to about 0.73 and an article comprising a substrate and, coated on the substrate, a thin film of the pyrochlore are provided. Also provided is a process for depositing on a substrate the above pyrochlore thin film. The process includes the steps of coating the substrate with a composition comprising bismuth carboxylate, zinc carboxylate, niobium alkoxide, an organic solvent, an organic acid and an organic base, heating to remove organic components and annealing at a temperature and for a length of time sufficient to produce the pyrochlore thin film on the substrate.
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