发明名称 Process for the preparation of organic compounds with manganese cataylsts or the like
摘要 A process of the present invention produces an organic compound by allowing a compound containing an electron attractive group of following Formula (1): wherein Y is an electron attractive group; and Rb and Rc are each a hydrogen atom or an organic group, where Y, Rb and Rc may respectively be combined with each other to form a ring with an adjacent carbon atom, to react with a compound containing an unsaturated carbon-carbon bond of following Formula (2) or wherein Rd, Re, Rf, Rg, Ri and Rj are each a hydrogen atom or an organic group, where Rd, Re, Rf and Rg may respectively be combined to form a ring with one or two adjacent carbon atoms, and Ri and Rj may be combined to form a ring with adjacent two carbon atoms, in the presence of oxygen and a catalytic compound of a Group 5, 6, 7, 8 or 9 element of the Periodic Table of Elements to yield a compound of following Formula (3) or (8): wherein Z is a hydrogen atom or a hydroxyl group; and Y, Rb, Rc, Rd, Re, Rf, Rg, Ri and Rj have the same meanings as defined above. This process can efficiently produce a compound having an alkyl group or alkenyl group bonded at the alpha position of an electron attractive group, or a derivative thereof, by catalytic radical addition reaction.
申请公布号 US2002165416(A1) 申请公布日期 2002.11.07
申请号 US20010959843 申请日期 2001.11.09
申请人 ISHII YASUTAKA;IWAHAMA TAKAHIRO;SAKAGUCHI SATOSHI;NAKANO TATSUYA 发明人 ISHII YASUTAKA;IWAHAMA TAKAHIRO;SAKAGUCHI SATOSHI;NAKANO TATSUYA
分类号 C07C45/33;C07C45/69;C07C51/56;C07C67/347;C07C253/30;C07C255/04;C07D307/20;C07D307/33;C07D307/83;C07D313/04;(IPC1-7):C0737/20;C07C45/28;C07C27/10 主分类号 C07C45/33
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