| 摘要 |
1,237,385. Metalated polyphenylene ethers. GENERAL ELECTRIC CO. 2 Oct., 1968 [5 Oct., 1967], No. 46870/68. Heading C3R. Polyphenylene ethers containing units of formula where X is hydrogen or halogen and each R is hydrogen, halogen, alkyl free of a tertiary carbon atom or aryl, are reacted with alkali metal alkyls or alkali metal aryls to obtain metalated polyphenylene ethers containing units of at least one of the formulµ where M is an alkali metal and R<SP>1</SP> is hydrogen, alkyl or aryl. Unreacted units also may be present in the polymer. When R in formulµ B and C is alkyl the metal M is lithium. The metalated polymers are reactive and may be converted to other derivatives. In examples, butyl lithium is reacted with brominated poly- (2,6-diphenyl-1,4-phenylene ether), with poly- (2,6-diphenyl-1,4-phenylene ether) and with poly - (2,6 - dimethyl - 1,4 - phenylene ether), and poly - (2,6 - dimethyl - 1,4 - phenylene ether) is reacted with the potassium derivative of α-methyl styrene and with hexyl potassium; in some instances amines are added as catalysts; the metalated polymers are reacted with methyldiphenylchlorosilane to replace the metal atoms by methyl-diphenylsilyl group, with carbon dioxide to replace the metal atoms by carboxyl groups, with iodine to replace the metal atoms by iodine atoms with dimethyl sulphate to replace the metal atoms by methyl groups and with trimethyl-chlorosilane to replace the metal atoms by trimethylsilyl groups. |
