发明名称 SiAION MATERIAL AND CUTTING TOOLS MADE THEREOF
摘要 This invention discloses a SiAION-based ceramic particularly suited for use as a cutting tool in the high speed chip forming machining of metals. The ceramic is composed of a SiAION matrix including a) a phase of alpha' SiAION represented by the general formula of Mx(Si,AL)12(O,N)16, wherein 0<x<2 and M is at least two cationic elements, a first cationic element being Mg and optionally one or more of Ca, Sr, and Ba, and a second cationic element being one or more of Y, Sc, La and the rare earth (RE) elements; b) a phase consisting of beta' SiAION represented by the general formula Si6-z AIzOzN8-z wherein 0<z<4.2; and c) a component containing glass, and at least one additional intergranular crystal phase that is detectable using X-ray diffraction techniques, wherein the amount of the first cationic element is 0.2 to 4 weight percent, calculated as the element, based on the SiAION matrix, and the amount of the second cationic element of between 0.5 and 15 weight percent, calculated as oxide, based on the SiAION matrix. The ceramic preferably has an indentation fracture toughness of greater than 6.5 MPam<1/2> and a hardness of greater than 93.5 Rockwell on the A scale. Optionally, the ceramic may also contain a dispersed phase of substantially inert materials selected from the known oxides, carbides, oxy-carbides, silicides, nitrides, carbo-nitrides and alloys or mixtures thereof of one or more of the element Ti, Zr, Hg, Nb, Ta, V, Cr, Mo, W, B and Si. The ceramic may be formed into a cutting tool insert for metal machining. Methods of preparing the ceramic material, most preferably by microwave sintering, are also provided. the use of microwave sintering is found to improve both the hardness and toughness properties, while avoiding the need for pressure sintering. The ceramic, or the cutting tool insert formed from the ceramic, may be provided with a partial or complete coating of a hard refractory material.
申请公布号 WO0228800(A3) 申请公布日期 2002.10.03
申请号 WO2001CA01385 申请日期 2001.10.01
申请人 INDEXABLE CUTTING TOOLS OF CANADA LIMITED;ROY, ROBERT, DONALD;ALLAN, DAVID 发明人 ROY, ROBERT, DONALD;ALLAN, DAVID
分类号 C04B35/597 主分类号 C04B35/597
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