发明名称 OSMIUM OXIDE DEPOSITED ON HYDROPHILIC POLYMER SUPPORT
摘要 A support for osmium oxide supporting which comprises an aromatic polyolefin having a group represented by the general formula [1] -A'-O(-A-O)n-R [1] (wherein A represents alkylene; A' represents a bond or alkylene; R represents aryl; and n is an integer of 1 to 10); osmium oxide deposited on the support; and a process for producing the osmium oxide. Since the osmium oxide has been deposited on the support having a hydrophilic group, it enables a diol compound to be easily produced in a high optical yield through oxidation or asymmetric oxidation especially in a heterogeneous system. It is usable safely and effectively also in the reactions of compounds including those which have been difficult to react in a nonaqueous solvent system.
申请公布号 WO02072259(A1) 申请公布日期 2002.09.19
申请号 WO2002JP02179 申请日期 2002.03.08
申请人 WAKO PURE CHEMICAL INDUSTRIES, LTD.;KOBAYASHI, SHU 发明人 KOBAYASHI, SHU
分类号 B01J13/02;B01J23/46;B01J31/06;B01J31/28;C07B53/00;C07C29/48;C07C45/30;C07F15/00 主分类号 B01J13/02
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