摘要 |
A method for preparing a layered perovskite compound thin film having a film thickness and structure controlled at a monomolecular layer and capable of combining various layered perovskite compounds at the level of a monomolecular layer. The method a superlattice structure represented by the general formula A2MX4 where A is an organic ammonium molecule, M is a group 4 element or transition metal and X is halogen layers of organic ammonium molecule "A" and layers of inorganic halide "MX4" are alternately stacked. A monomolecular film of an organic amine hydrohalic acid salt having a long-chain alkyl group is spread out on the surface of a water solution of an inorganic halide MX2 and a methylamine hydrohalic acid salt. By leaving the monomolecular film, a layered perovskite compound monomolecular film is formed on the surface of the water solution. This layered perovskite monomolecular film is transferred and stacked onto a substrate on a one by one basis by using the Langmuir-Blodgett method.
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